Cavity effect amplification in the recognition of dicarboxylic acids by initial ditopic H-bond formation followed by kinetic trapping.
نویسندگان
چکیده
Di[dihydroxotin(IV)] Tröger's base bis-porphyrin 1, a host molecule with two internal and two external guest interaction sites, binds <or= 1 equivalent of dicarboxylic acid quantitatively within the chiral cavity, a regioselectivity amplified by initial ditopic H-bond formation, followed by kinetic trapping.
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ورودعنوان ژورنال:
- Chemical communications
دوره 3 شماره
صفحات -
تاریخ انتشار 2007